Radioactivity

An unstable nucleus emits energetic particles or waves and the unstable nucleus transforms to some other nucleus or energy level. This is referred to as radioactive decay. Three types of radioactive decay occur in nature:

(i) Alpha decay in which a helium nucleus is emitted;
(ii) Beta decay in which electrons or positrons (particles with the same mass as electrons, but with a charge exactly opposite to that of electron) are emitted;
(iii) Gama decay in which high energy (hundreds of keV or more) photons are emitted.

Law of radioactive decay

The number of nuclei undergoing the decay per unit time is proportional to the total number of nuclei in the sample. If N is the number of nuclei in the sample and ΔN undergo decay in time Δt then
\[\frac{\Delta N }{\Delta t}= \lambda N\] 

 Where λ is called the radioactive decay constant or disintegration constant. The change in the number of nuclei in the sample is dN = – ΔN in time Δt. Thus the rate of change of N is (in the limit Δt → 0)
 \[\frac{dN }{dt}=- \lambda N\] \[\Rightarrow \frac{dN}{N}=-\lambda dt\]  
Integrating we get,
 \[\Rightarrow\int_{N_{0}}^{N} \frac{dN}{N}=-\lambda \int_{0}^{t}dt\]
 \[\Rightarrow ln\frac{N}{N_{0}}=-\lambda t\]
 \[\therefore N(t)=N_{0}e^{-\lambda t}\]
The above equation represents the law of radioactivity.The SI unit for radioactive decay is Becquerel (Bq). Where 1Bq=1 decay per second. Old unit for radioactive decay was Curie. 1 Curie = 3.7 x 1010 Bq

Half-life (T1/2) of a radionuclide is the time at which a radioactive sample has been reduced to one-half its’ initial quantity.
\[\therefore \frac{N_{0}}{2}=N_{0}e^{-\lambda T_{\frac{1}{2}}}\]
 \[\Rightarrow T_{\frac{1}{2}}=\frac{ln2}{\lambda }=\frac{0.693}{\lambda }\]