Limitations of Ohm's Law and Variation of Resistivity

Limitations of Ohm's Law: Although Ohm’s law has been found valid over a large class of materials, there are a number of commonly used circuit elements which do not obey this law called Non – Ohmic conductors.

Non – Ohmic conductors have one or more of the following properties:

1. Potential difference (V) depends on current (I) non-linearly.
2. The relation between V and I is non-unique, that is, for the same current I, there is more than one value of voltage V. 
3. The relationship between V and I depends on the sign of V for the same absolute value of V.


Variation of Resistivity with Temperature: The resistivity of a material is temperature dependent. All materials do not exhibit the same dependence on temperatures. Over a limited range of temperatures, that is not too large, the resistivity of a metallic conductor is approximately given by,

ρT = ρo [1 + α (T–To)]


Where ρT is the resistivity at a temperature T and ρo is the same at a reference temperature To. α is called the temperature co-efficient of resistivity, and SI unit of α is K–1.